Nano-Micro Letters, Volume. 16, Issue 1, 093(2024)

Novel Perovskite Oxide Hybrid Nanofibers Embedded with Nanocatalysts for Highly Efficient and Durable Electrodes in Direct CO2 Electrolysis

Akromjon Akhmadjonov1,†... Kyung Taek Bae1,†, and Kang Taek Lee12,* |Show fewer author(s)
Author Affiliations
  • 1Department of Mechanical Engineering, KAIST, Daejeon 34141, Republic of Korea
  • 2KAIST Graduate School of Green Growth and Sustainability, Daejeon, 34141, Republic of Korea
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    The unique characteristics of nanofibers in rational electrode design enable effective utilization and maximizing material properties for achieving highly efficient and sustainable CO2 reduction reactions (CO2RRs) in solid oxide electrolysis cells (SOECs). However, practical application of nanofiber-based electrodes faces challenges in establishing sufficient interfacial contact and adhesion with the dense electrolyte. To tackle this challenge, a novel hybrid nanofiber electrode, La0.6Sr0.4Co0.15Fe0.8Pd0.05O3-δ (H-LSCFP), is developed by strategically incorporating low aspect ratio crushed LSCFP nanofibers into the excess porous interspace of a high aspect ratio LSCFP nanofiber framework synthesized via electrospinning technique. After consecutive treatment in 100% H2 and CO2 at 700 °C, LSCFP nanofibers form a perovskite phase with in situ exsolved Co metal nanocatalysts and a high concentration of oxygen species on the surface, enhancing CO2 adsorption. The SOEC with the H-LSCFP electrode yielded an outstanding current density of 2.2 A cm-2 in CO2 at 800 °C and 1.5 V, setting a new benchmark among reported nanofiber-based electrodes. Digital twinning of the H-LSCFP reveals improved contact adhesion and increased reaction sites for CO2RR. The present work demonstrates a highly catalytically active and robust nanofiber-based fuel electrode with a hybrid structure, paving the way for further advancements and nanofiber applications in CO2-SOECs.

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    Akromjon Akhmadjonov, Kyung Taek Bae, Kang Taek Lee. Novel Perovskite Oxide Hybrid Nanofibers Embedded with Nanocatalysts for Highly Efficient and Durable Electrodes in Direct CO2 Electrolysis[J]. Nano-Micro Letters, 2024, 16(1): 093

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    Paper Information

    Category: Research Articles

    Received: Jul. 24, 2023

    Accepted: Nov. 25, 2023

    Published Online: Jan. 23, 2025

    The Author Email: Lee Kang Taek (leekt@kaist.ac.kr)

    DOI:10.1007/s40820-023-01298-w

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