Chinese Journal of Quantum Electronics, Volume. 23, Issue 6, 802(2006)

Photodissociation spectra of the complex Mg+-S2(CH3)2

Hua WU*... Yi-hua HU, Jia-yong LIN, Ren CHEN and Li CHEN |Show fewer author(s)
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    Photodissociation spectra of the complex Mg+-S2(CH3)2 in the spectral region of 230~440 nm was observed. Mass spectrometry of the products for photo-induced reaction in the complex Mg+-S2(CH3)2 exhibits the product Mg+ from nonreaction quenching and reactive products Mg+-SCH3 throughout the whole wavelength range. The reactive products originate from the rupture of S-S chemical bonds. The photo dissociation spectrum consists of two broad peaks corresponding to the atomic transition of Mg+(32P←32S). The absorption spectrum by CIS method of quantum chemistry calculation agrees with the experimental spectrum.

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    WU Hua, HU Yi-hua, LIN Jia-yong, CHEN Ren, CHEN Li. Photodissociation spectra of the complex Mg+-S2(CH3)2[J]. Chinese Journal of Quantum Electronics, 2006, 23(6): 802

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    Paper Information

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    Received: Nov. 7, 2005

    Accepted: --

    Published Online: Jun. 7, 2010

    The Author Email: Hua WU (wh1125@126.com)

    DOI:

    CSTR:32186.14.

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