Journal of Inorganic Materials, Volume. 39, Issue 6, 726(2024)

Microstructure and Properties of C/HfC-SiC Composites Prepared by Slurry Impregnation Assisted Precursor Infiltration Pyrolysis

Yi SU1, Yangfan SHI1, Chenglan JIA1, Pengtao CHI2, Yang GAO2, Qingsong MA1, and Sian CHEN1、*
Author Affiliations
  • 11. Science and Technology on Advanced Ceramic Fibers &Composites Laboratory, National University of Defense Technology, Changsha 410073, China
  • 22. Science and Technology on Space Physics Laboratory, China Academy of Launch Vehicle Technology, Beijing 100076, China
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    In response to the urgent demand for ultra-high temperature ceramic matrix composites with integrated thermal protection and load-bearing capabilities for high-speed aircrafts, this study prepared stable ceramic slurry from submicron HfC ceramic powder, and utilized the slurry pressure impregnation-assisted precursor infiltration pyrolysis (PIP) process to fabricate C/HfC-SiC composites with uniformly distributed HfC matrix to overcome the shortcomings of the existing reaction-derived HfC precursor, such as high cost, low efficiency, and poor densification effect. The influence of HfC content on the microstructure, mechanical properties, and ablation resistance of composites was investigated. Results showed that the composites had density of 2.20-2.58 g·cm-3 and open porosity of approximately 5% when the actual volume fraction of HfC was in range of 13.1%-20.3%. Utilizing a single layer of carbon cloth to impregnate the ceramic slurry with pressure, HfC particles were able to disperse into the interior of the fiber bundle and distributed relatively evenly in the composites. Increasing the HfC content resulted in reducted fiber content, and decreased mechanical properties of composites. Specifically, when HfC volume fraction was 20.3%, the composites exhibited density, tensile strength and fracture toughness of 2.58 g·cm-3, 147 MPa and 9.3 MPa·m1/2, respectively. Following 60 s of ablation under an oxygen acetylene flame, the composites demonstrated linear ablation rate of 0.0062 mm/s and mass ablation rate of 0.005 g/s. The molten phase HfxSiyOz formed during the ablation process could effectively cover the composites surface and provide protection.

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    Yi SU, Yangfan SHI, Chenglan JIA, Pengtao CHI, Yang GAO, Qingsong MA, Sian CHEN. Microstructure and Properties of C/HfC-SiC Composites Prepared by Slurry Impregnation Assisted Precursor Infiltration Pyrolysis[J]. Journal of Inorganic Materials, 2024, 39(6): 726

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    Paper Information

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    Received: Oct. 13, 2023

    Accepted: --

    Published Online: Jul. 31, 2024

    The Author Email: CHEN Sian (chensian07@nudt.edu.cn)

    DOI:10.15541/jim20230471

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