Equal channel angular pressing (ECAP) followed by heat treatment was carried out to prepare Ag/Ti₃AlC₂ composites. Effects of heat treatment on the electrical resistivities and mechanical properties of the Ag/Ti₃AlC₂ composites were investigated. Results show that ECAP effectively densifies the Ag/Ti₃AlC₂ compacts, and layered Ti₃AlC₂ particles are delaminated and aligned due to shearing effect during ECAP. Alignment of Ti₃AlC₂ particles resulted in anisotropy of electrical and mechanical properties of the composites. Perpendicular to the alignment of Ti₃AlC₂ particles displayed high resistivity and compressive strength. Moreover, resistivity and compressive strength increased with following heat treatment, yielding the maximum at 800 ℃. These increments are attributed to the enhanced interfacial reactions between Ag and Ti₃AlC₂ at high temperatures. Findings in this study indicate that densification and microstructural control of Ag/MAX composites can be achieved simultaneously by ECAP, while the following heat treatment can tailor their properties.