Spectroscopy and Spectral Analysis, Volume. 29, Issue 9, 2577(2009)

Methodology Improvement in Background Elimination in Plant Cd Measurement by Graphite Furnace Atom Absorption

YU Hua*, FENG Wen-qiang, QIN Yu-sheng, CHEN Qing-rui, ZENG Xiang-zhong, and TU Shi-hua
Author Affiliations
  • [in Chinese]
  • show less

    A problem of higher background value and lower measured Cd value exists when Cd is digested by conventional dry digestion method, measured by graphite furnace atomic absorption, and calculated with peak height numeration. This problem results in difficulty for evaluating samples with Cd contents in the neighborhood of critical values. In order to solve the problem, the present paper focused on background measurement with graphite furnace atomic absorption, modified the pre-preparation procedures of the traditional method, and screened the optimal concentration of the modifier. Results showed that addition of Mg(NO3)2 as a modifier into the samples before incineration was preferred. It could not only yield a clear solution but also reduce its background by ten times, considerably eliminating background interference. In addition, using 3% HNO3 in stead of 1 mol·L-1 HCl as dilution for the incinerated sample could eliminate the background. The improved methods could acquire a zero concentration of measurement for the blank, re-correct the values measured by graphite furnace atomic absorption and obtain more reliable results.

    Tools

    Get Citation

    Copy Citation Text

    YU Hua, FENG Wen-qiang, QIN Yu-sheng, CHEN Qing-rui, ZENG Xiang-zhong, TU Shi-hua. Methodology Improvement in Background Elimination in Plant Cd Measurement by Graphite Furnace Atom Absorption[J]. Spectroscopy and Spectral Analysis, 2009, 29(9): 2577

    Download Citation

    EndNote(RIS)BibTexPlain Text
    Save article for my favorites
    Paper Information

    Received: Aug. 20, 2008

    Accepted: --

    Published Online: May. 26, 2010

    The Author Email: Hua YU (yuhua353@163.com)

    DOI:

    Topics