Platinum (Pt) was encapsulated in ZSM-5 by an one-step hydrothermal method for dehydrogenation of propane to prepare propylene (PDH). The catalysts were characterized by X-ray diffraction, specific surface area measurement, H2-pluse, scanning electron microscopy and transmission electron microscopy. Under the optimal reaction conditions, the propane conversion and propylene selectivity are 48% and 57%. In addition, the catalytic system can also resist the toxic effect of DBT, and the propane conversion and propylene selectivity are not reduced with DBT containing a catalytic system.