Spectroscopy and Spectral Analysis, Volume. 30, Issue 1, 18(2010)
Study of Spectra Characteristics of Dy3+-Activated LiSrBO3 Phosphor
The LiSrBO3:Dy3+ phosphor was synthesized by solid-state method. SrCO3(99.9%),Li2CO3(99.9%),H3BO3(99.9%) and Dy2O3(99.9%) were used as starting materials. After these individual materials were blended and grounded thoroughly in an agate mortar,the homogeneous mixture was heated at 700 ℃ for 2 h in air,and LiSrBO3:Dy3+ phosphors were obtained. The phase present of the samples was characterized by powder X-ray diffraction (XRD) (D/max-rA,Cu Kα,40 kV,40 mA,λ=0.154 06 nm). The excitation and emission spectra of these phosphors were measured by a RF-540 photoluminescence spectrophotometer. The emission spectrum of LiSrBO3:Dy3+ phosphor shows several bands at 486,578 and 668 nm,respectively. The excitation spectrum for 578 nm emission has several excitation bands at 331,368,397,433,462 and 478 nm,respectively. The effect of Dy3+ concentration on the emission intensity of LiSrBO3:Dy3+ was investigated,and the result shows that the emission intensity of LiSrBO3:Dy3+ phosphor firstly increases with increasing Dy3+ concentration,then decreases,viz. the concentration quenching exists. And the Dy3+ concentration corresponding to the maximal emission intensity is 3 mol%,and the concentration quenching mechanisms are the d-d interaction by Dexter theory.
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WANG Zhi-jun, LI Pan-lai, PANG Li-bin, YANG Zhi-ping1, GUO Qing-lin, FU Guang-sheng, LI Xu. Study of Spectra Characteristics of Dy3+-Activated LiSrBO3 Phosphor[J]. Spectroscopy and Spectral Analysis, 2010, 30(1): 18
Received: Dec. 6, 2008
Accepted: --
Published Online: Jul. 13, 2010
The Author Email: Zhi-jun WANG (wangzhijunmail@yahoo.com.cn)