Journal of Synthetic Crystals, Volume. 53, Issue 11, 1892(2024)

Fabrication and Properties of Er∶Lu2O3 Transparent Ceramics with Different Doping Concentrations

LIU Ziyu1...2, ZHENG Wenwen1, FENG Yagang3, YE Junhao2,4, LIU Peng1, YANG Xianfeng1,*, and LI Jiang24 |Show fewer author(s)
Author Affiliations
  • 1School of Materials Science and Engineering, Changsha University of Science & Technology, Changsha 410004, China
  • 2Transparent Ceramics Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
  • 3School of Material Science and Engineering, Henan University of Technology, Zhengzhou 450001, China
  • 4Center of Materials Science and Optoelectronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China
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    Er∶Lu2O3 transparent ceramics are one of the candidate solid-state gain media for high efficiency and high power laser in the near and mid-infrared bands due to the advantages of high thermal conductivity, high thermal shock resistance, good spectral properties and low preparation temperature. Exploring the influence of Er3+ doping concentration (atomic number fraction) on the preparation and properties of Er∶Lu2O3 transparent ceramics for the related laser application is crucial for achieving high-quality Er∶Lu2O3 ceramics. In this paper, Er∶Lu2O3 transparent ceramics were fabricated using vacuum pre-sintering combined with hot isostatic pressing (HIP) post-treatment from the nano-powders synthesized by the coprecipitation method. The results show that the phases of all Er∶Lu2O3 nano-powders calcined at 1 100 ℃ with different Er3+ concentrations are almost consistent with that of the pure cubic Lu2O3 and the 10% Er∶Lu2O3 nano-powder shows better dispersibility. The average grain sizes of 0.3% and 10% Er∶Lu2O3 ceramics pre-sintered at 1 500 ℃ are 0.86 and 0.87 μm with the relative densities of 95.1% and 96.2%, respectively. The corresponding pre-sintered ceramics were HIP-ed at 1 750 ℃ show the in-line transmittance of 71.6% and 78.0% (thickness 2.9 mm) at 2 400 nm, respectively. Especially, the in-line transmittance of the 0.3% Er∶Lu2O3 ceramics sharply decreases in the short wave range due to the numerous remained residual pores. The absorption and emission spectra of 0.3% and 10% Er∶Lu2O3 transparent ceramics were calculated. 0.3% Er∶Lu2O3 ceramics possesses higher absorption and emission cross-sections around the band centered at 1.55 μm.

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    LIU Ziyu, ZHENG Wenwen, FENG Yagang, YE Junhao, LIU Peng, YANG Xianfeng, LI Jiang. Fabrication and Properties of Er∶Lu2O3 Transparent Ceramics with Different Doping Concentrations[J]. Journal of Synthetic Crystals, 2024, 53(11): 1892

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    Paper Information

    Category:

    Received: Sep. 10, 2024

    Accepted: Jan. 2, 2025

    Published Online: Jan. 2, 2025

    The Author Email: Xianfeng YANG (yangxfcsust@csust.edu.cn)

    DOI:

    CSTR:32186.14.

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