Acta Physica Sinica, Volume. 69, Issue 12, 127701-1(2020)

Influence of electric field on the phenomenological coefficient and electrocaloric strength in ferroelectrics

Sheng-Guo Lu1,2、*, Dan-Dan Li1, Xiong-Wei Lin1,2, Xiao-Dong Jian1,2, Xiao-Bo Zhao1, Ying-Bang Yao1,2, Tao Tao1,2, and Bo Liang1,2
Author Affiliations
  • 1Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, Guangdong Provincial Research Center on Smart Materials and Energy Conversion Devices, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
  • 2Dongguan South China Design Innovation Institute, Dongguan 523808, China
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    As the electric field can affect the polarization and dielectric constant, the phenomenological coefficient a0 is an implicit function of electric field. The phenomenological coefficient a0 is determined by the polarization and the reciprocal of permittivity, and a nonlinear function of electric field in the ferroelectric phase regime. In the paraelectric phase regime, however, a0 is merely subjected to the reciprocal of permittivity, and also a nonlinear function of electric field. In this paper, we investigate the electric field dependence of phenomenological coefficient in ferroelectric copolymers, terpolymers and Ba0.85Ca0.05Sr0.1TiO3 ceramics. It is indicated that the phenomenological coefficient increases with the increasing electric field, the maximum value is obtained to be about 2 times the original value. Moreover, the electrocaloric strength is used to measure the magnitude of electrocaloric effect of electrocaloric materials in an external electric field. It can be used to find out novel and efficient electrocaloric materials through studying the electrocaloric strength. Based on the thermodynamic theory, the analytical expression of electrocaloric strength is deduced. It is found that the phenomenological coefficient, phase transition, specific heat capacity, and permittivity versus temperature peak value at the phase transition temperature have a clear influence on the electrocaloric strength. The expression can be applied to 1st order, 2nd order phase transition materials and relaxor ferroelectrics.

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    Sheng-Guo Lu, Dan-Dan Li, Xiong-Wei Lin, Xiao-Dong Jian, Xiao-Bo Zhao, Ying-Bang Yao, Tao Tao, Bo Liang. Influence of electric field on the phenomenological coefficient and electrocaloric strength in ferroelectrics[J]. Acta Physica Sinica, 2020, 69(12): 127701-1

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    Paper Information

    Received: Feb. 27, 2020

    Accepted: --

    Published Online: Dec. 8, 2020

    The Author Email:

    DOI:10.7498/aps.69.20200296

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