Acta Photonica Sinica, Volume. 40, Issue 6, 902(2011)

Orientation Mode of Azobenzene Mesogens and Their Effects on the Orientation Stability

LIU Jian*, WANG Ming-le, GAO Liu-de, DONG Ming-ling, and TIAN Jing-jing
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    Out-of-plane and in-plane reorientations of mesogens were observed upon a linearly polarized light irradiation of azobenzene containing side-chain liquid crystalline polymer, which were characterized by the transmission various and polarized optical microscopy observation of the pumped film. Higher power density polarized light (20 mW/cm2) irradiation on the film induces that a maximal value of the photoinduced transmission is firstly obtained and then a decrease in the transmission value was observered. This suggests an out-of-plain orientation happened. Out-of-plane orientation decreases the stability of the oriented mesogens, which is confirmed by the lost of the anisotropy when the exposure light turn-off. The in-plane and out-of-plane reorientation depend on the laser fluence. The photoinduced anisotropy measurements results reveal that a stable orientation occurred by using an unsaturated irradiation upon a low power density laser beam. The unsaturated irradiation enables to shorten 95% of the incident time and increases the orientation order 1.3 times as compared to that of full orientation. A quick and high stable bit recording is achieved by unsaturated orientation upon 4 ms light irradiation.

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    LIU Jian, WANG Ming-le, GAO Liu-de, DONG Ming-ling, TIAN Jing-jing. Orientation Mode of Azobenzene Mesogens and Their Effects on the Orientation Stability[J]. Acta Photonica Sinica, 2011, 40(6): 902

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    Paper Information

    Received: Dec. 3, 2010

    Accepted: --

    Published Online: Jun. 24, 2011

    The Author Email: Jian LIU (jianliu@swust.edu.cn)

    DOI:10.3788/gzxb20114006.0902

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