Acta Optica Sinica, Volume. 30, Issue 5, 1422(2010)

2 μm Emission Properties of Tm3+-Doped Fluorozirconate Glass

Zhang Junjie*, Yu Chunlei, Lai Yangqiong, Zhang Liyan, and Hu Lili
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    2 μm emission properties of Tm3+ in fluorozirconate glass were reported. The Judd-Ofelt (J-O) intensity parameters Ωt (t=2,4,6),spontaneous emission probability,fluorescence branching ratio,and the radiative lifetime were calculated on the basis of Judd-Ofelt theory by measuring the absorption spectra of the glass. The effects of Tm3+ ion concentration on the optical parameters were discussed. From the measured emission spectra of glass,it was found that the peak wavelength of Tm3+:3F4→3H6 transition is located at 1.82 μm in the Tm3+-doped fluorozirconate glass. It was also found that the cross relaxation (3H4→3F4,3F4→3H6) between the Tm3+ ions occurred with the Tm3+ ion concentration increasing,which leads to the increasing magnitude of 3F4→3H6 transition. Due to the concentration quenching mechanism of three-energy level ions,the intensity of luminescence decreased obviously. The stimulated emission cross section of Tm3+:3F4→3H6 transition was calculated by using Mcumber theory. The results show that doping concentration has little effect on the emission cross section of Tm3+ in the present fluorozirconate glass.

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    Zhang Junjie, Yu Chunlei, Lai Yangqiong, Zhang Liyan, Hu Lili. 2 μm Emission Properties of Tm3+-Doped Fluorozirconate Glass[J]. Acta Optica Sinica, 2010, 30(5): 1422

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    Paper Information

    Category: Materials

    Received: Sep. 3, 2009

    Accepted: --

    Published Online: May. 11, 2010

    The Author Email: Junjie Zhang (jjzhang@mail.siom.ac.cn)

    DOI:10.3788/aos20103005.1422

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