GHz burst-mode femtosecond (fs) laser, which emits a series of pulse trains with extremely short intervals of several hundred picoseconds, provides distinct characteristics in materials processing as compared with the conventional irradiation scheme of fs laser (single-pulse mode). In this paper, we take advantage of the moderate pulse interval of 205 ps (4.88 GHz) in the burst pulse for high-quality and high-efficiency micromachining of single crystalline sapphire by laser induced plasma assisted ablation (LIPAA). Specifically, the preceding pulses in the burst generate plasma by ablation of copper placed behind the sapphire substrate, which interacts with the subsequent pulses to induce ablation at the rear surface of sapphire substrates. As a result, not only the ablation quality but also the ablation efficiency and the fabrication resolution are greatly improved compared to the other schemes including single-pulse mode fs laser direct ablation, single-pulse mode fs-LIPAA, and nanosecond-LIPAA.

Phonon polaritons (PhPs) exhibit directional in-plane propagation and ultralow losses in van der Waals (vdW) crystals, offering new possibilities for controlling the flow of light at the nanoscale. However, these PhPs, including their directional propagation, are inherently determined by the anisotropic crystal structure of the host materials. Although in-plane anisotropic PhPs can be manipulated by twisting engineering, such as twisting individual vdW slabs, dynamically adjusting their propagation presents a significant challenge. The limited application of the twisted bilayer structure in bare films further restricts its usage. In this study, we present a technique in which anisotropic PhPs supported by bare biaxial vdW slabs can be actively tuned by modifying their local dielectric environment. Excitingly, we predict that the iso-frequency contour of PhPs can be reoriented to enable propagation along forbidden directions when the crystal is placed on a substrate with a moderate negative permittivity. Besides, we systematically investigate the impact of polaritonic coupling on near-field radiative heat transfer (NFRHT) between heterostructures integrated with different substrates that have negative permittivity. Our main findings reveal that through the analysis of dispersion contour and photon transmission coefficient, the excitation and reorientation of the fundamental mode facilitate increased photon tunneling, thereby enhancing heat transfer between heterostructures. Conversely, the annihilation of the fundamental mode hinders heat transfer. Furthermore, we find the enhancement or suppression of radiative energy transport depends on the relative magnitude of the slab thickness and the vacuum gap width. Finally, the effect of negative permittivity substrates on NFRHT along the [001] crystalline direction of α-MoO3 is considered. The spectral band where the excited fundamental mode resulting from the negative permittivity substrates is shifted to the first Reststrahlen Band (RB 1) of α-MoO3 and is widened, resulting in more significant enhancement of heat flux from RB 1. We anticipate our results will motivate new direction for dynamical tunability of the PhPs in photonic devices.